Synthesis and structure of the hexameric, dodecanuclear metallamacrocycle [(5-methyl-3-phenylpyrazole)2Zn2(OCH2CH2S)]6.

نویسندگان

  • David T Puerta
  • Seth M Cohen
چکیده

A metallamacrocycle containing twelve Zn2+ ions, making it the largest member of a family of pyrazole-bridged cyclic metal clusters, has been synthesized and structurally characterized from the reaction of [Zn(ClO4)2] with 5-methyl-3-phenylpyrazole, 2-mercaptoethanol, and NaOH.

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عنوان ژورنال:
  • Chemical communications

دوره 11  شماره 

صفحات  -

تاریخ انتشار 2003